Posts Tagged ‘Clar islands’

Clar islands in a π Cloud

Wednesday, December 9th, 2009

Clar islands are found not so much in an ocean, but in a type of molecule known as polycyclic aromatic hydrocarbons (PAH). One member of this class, graphene, is attracting a lot of attention recently as a potential material for use in computer chips. Clar coined the term in 1972 to explain the properties of PAHs, and the background is covered in a recent article by Fowler and co-workers (DOI: 10.1039/b604769f). The concept is illustrated by the following hydrocarbon:

(more…)

A molecule with an identity crisis: Aromatic or anti-aromatic?

Monday, April 13th, 2009

In 1988, Wilke (DOI: 10.1002/anie.198801851) reported molecule 1

(more…)